I'm like 99% sure that regardless of what octane you put in, as long as you keep using it the car will tune itself to deliver 138/148.
Premium != TOP Tier.
Premium == 91 || 93 etc.
TOP TIER == more detergents
Straight from the manual:
Fuel Additives
To provide cleaner air, all gasolines
in the United States are now
required to contain additives that
help prevent engine and fuel system
deposits from forming, allowing the
emission control system to work
properly. In most cases, nothing
should have to be added to the fuel.
However, some gasolines contain
only the minimum amount of
additive required to meet U.S.
Environmental Protection Agency
regulations. To help keep fuel
injectors and intake valves clean
and avoid problems due to dirty
injectors or valves, look for gasoline
that is advertised as TOP TIER
Detergent Gasoline. Look for the
TOP TIER label on the fuel pump to
ensure gasoline meets enhanced
detergency standards developed
by the auto companies. A list of
marketers providing TOP TIER
Detergent Gasoline can be found at
Home | Top Tier Gas.
For customers who do not use TOP
TIER Detergent Gasoline regularly,
one bottle of GM Fuel System
Treatment PLUS, added to the fuel
tank at every engine oil change,
can help clean deposits from fuel
injectors and intake valves. GM Fuel
System Treatment PLUS is the only
gasoline additive recommended by
General Motors. It is available at
your dealer.
Idk about octane boosters though. From my research though I don't think octane boosters would help enough to actually make a difference.