Sure you will see some differences between stations, but the route, weather and driving style have much more effect. I always try to fill at a high volume stations near the cross roads of major highways.
98% of the premium in my are is 91 octane no ethanol, which my cruze and now my sonic seem to hate. Car runs much better on the cheaper 93 octane 10% ethanol found at many other stations. I can fill up at BP, Shell, Mobil and only get 91 octane, drive 10 miles and get 93 octane from the same brands. Seems random which stations have 93 here.
We even have a few pumps here(mobil and shell brand) with two premium grades, 91E0 on one hose, 87E10,89E10 and 93E10 on another.