Scot
Athletic Supporter
Nice write up Pre!
The vapor you smell at hot start could be attributed to the EVAP system. It has a solenoid that allows fuel vapors from the gas tank to be re-ingested by the engine via the intake manifold as pressure builds in the tank. The vapors are filtered through a charcoal canister that sometimes resides under the hood, but the more recent trend seems to be to put them closer to the fuel tank. If that system is malfunctioning, it could be venting tank vapor and that would cause your smell.
Just catching up on reading and noticed this.
This isn't quite how it works - mostly true - but not entirely.
The canister has three ports: Load, vent and purge. Since 1998, passenger cars have had to use an "On-board Refueling Vapor Recovery" (ORVR) system. Some of you remember the vacuum bellows that used to be on gasoline dispensing nozzles - that was to catch vapors (fumes) while you were refueling - and stored onsite at the station. Well... Oil companies have more lobbyists than auto makers, and it was decided the auto manufacturers would be responsible for catching vapors while refueling. :blankface:
So - now, we use skinny fill pipes, and an assortment of valves that create a vacuum at the filler neck when you pump gasoline into your car. The vacuum pulls surrounding air and any vapor generated into the tank. This creates a positive pressure in the vapor dome (area above the liquid fuel) of the tank. This pressure escapes through the canister which is filled with activated carbon; the carbon attracts the fuel molecules out of the vapor and vents fresh air out of the vent port. This way, hydrocarbons are trapped within the canister and not out into the atmosphere.
The volume of the canister is limited and can only hold so much hydrocarbons, so it is sucked clean - or "purged" - when the engine is running. You can't just always pull a vacuum on the canister: After a refueling even, there's enough fuel available through the purge system to run the engine - with the injectors turned off! So, there is a valve that purge flow is limited with, and the normal / failed state of the valve is in the closed position. I.E. It cannot cause a fuel smell while the engine is off.
Now, one thing that could cause it (besides PCV) could be a leaky injector. So, shut off the car, there's still high pressure in the fuel rail. It is possible for an injector to leak fuel as the engine sits. The fuel vapor can actually migrate through the entire intake system and exit the intake snorkel. I know this had to be a concern for GM - just because of the carbon pad that is in the stock airbox. That pad is a "bandaid" to prevent fuel vapor from escaping the intake system.